Place the first chocolate cake layer onto a cake board or serving plate.
Pipe a thick ring of vanilla buttercream around the outer edge of the cake to create a sturdy dam.
Spread approximately ½ to ¾ cup marshmallow creme inside the buttercream border.
Sprinkle a generous layer of mini marshmallows directly over the marshmallow creme.
Using a kitchen torch, carefully toast the marshmallow creme and mini marshmallows together directly on top of the cake layer until the marshmallows are golden and the creme develops lightly toasted, caramelized areas.
Allow the toasted filling to cool briefly before placing the next cake layer on top.
Place the second chocolate cake layer over the first.
Pipe another thick vanilla buttercream dam around the outer edge.
Spread another ½ to ¾ cup marshmallow creme inside the border.
Add another generous layer of mini marshmallows.
Torch the marshmallow creme and marshmallows together until toasted and lightly caramelized.
Allow the filling to cool briefly, then place the final chocolate cake layer on top.
Spread a thin layer of vanilla buttercream over the top and sides of the cake.
Use an offset spatula or cake scraper to smooth the crumb coat.